Map of Emission Mechanisms and Their Spectral Domains
Mechanism Typical spectral range Physical determinants Key feature
Photoluminescence Fluorescence Phosphorescence UV 200–400 nm; Vis 400–700 nm; NIR 700–1100 nm Bandgap, defect states, thermal quenching; quantum yield/lifetime Broad spectral engineering via materials/dopants
Chemiluminescence Bioluminescence Vis 430–600 nm; NIR 650–900 nm (probes) ΔG of reaction, excitation pathways, energy transfer “Cold” light; kinetic/thermochemical control
Triboluminescence Mechanoluminescence Vis 400–700 nm; sometimes NIR Charge separation upon fracture, micro‑discharge, host PL Spectrum close to host fluorescence
Radioluminescence Scintillation UV–Vis–NIR 200–900 nm LET, transfer to luminescent centers; non‑linearity (Birks’ law) Birks ∝ yield vs dE/dx (band set by host/dopant)
Thermoluminescence Vis ~350–650 nm Thermal release (E, s), kinetic (order 1/2) “Glow” curves vs T (dosimetry/archaeology)
Plasma discharge LTE non‑LTE Planck continuum (Wien λmax≈2.9×10−3/T)
Lines/bands UV–IR, VUV possible
Temperature, composition, pressure, opacity; equilibrium vs non‑LTE Continuum (opaque) or atomic/ionic emission lines
Sonoluminescence Vis–near-UV, peak ~300–500 nm (T≈4–10 kK) Adiabatic compression of a bubble, gas/opacity, stability window Quasi-thermal flash, micrometric, ultra-fast
Electroluminescence LED/OLED EL panel UV → NIR, by bandgap (≈315–950+ nm) Radiative e/hole recombination; material (InGaN, GaAsP, organics…) Color set by Eg (E=hc/λ); narrowband, efficient
Ranges are typical, not absolute; spectrum can shift with material or condition engineering.